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200050

Sigma-Aldrich

Chromium(III) chloride

purified by sublimation, 99%

Sinonimo/i:

Chromic chloride, Chromium trichloride

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About This Item

Formula condensata:
CrCl3
Numero CAS:
10025-73-7
Peso molecolare:
158.36
Numero CE:
233-038-3
Numero MDL:
MFCD00010948
Codice UNSPSC:
12352302
ID PubChem:
24851955
NACRES:
NA.23

Saggio

99%

Forma fisica

flakes

Purificato mediante

sublimation

Impiego in reazioni chimiche

reagent type: catalyst
core: chromium

Impurezze

<0.2% water

Densità

2.87 g/mL at 25 °C (lit.)

Stringa SMILE

Cl[Cr](Cl)Cl

InChI

1S/3ClH.Cr/h3*1H;/q;;;+3/p-3
QSWDMMVNRMROPK-UHFFFAOYSA-K

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Applicazioni

Chromium(III) chloride can be used in the formation of a catalytic system for the conversion of glucose into 5-hydroxymethylfurfural (HMF). It can also be used in the preparation of ionic liquid mixtures using choline chloride and water with improved ion mobility and conductivity.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.2

Avvertenze

Warning

Indicazioni di pericolo

H290,H302,H317,H411

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Met. Corr. 1 - Skin Sens. 1B

Codice della classe di stoccaggio

8B - Non-combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Certificati d'analisi (COA)

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Physicochemical properties of ionic liquid mixtures containing choline chloride, chromium (III) chloride and water: effects of temperature and water content
Protsenko VS, et al.
Ionics, 23(3), 637-643 (2017)
Efficient conversion of glucose into 5-hydroxymethylfurfural by chromium (III) chloride in inexpensive ionic liquid
Hu L, et al.
Industrial & Engineering Chemistry Research, 51(3), 1099-1104 (2012)
Yu-Fei Song et al.
Dalton transactions (Cambridge, England : 2003), (14)(14), 1864-1871 (2008-03-29)
The coordination chemistry of CrCl3 with three pentadentate ligands having the [1,4,7]-triazacyclononane-1,4-diacetato motif have been investigated. The new resulting six-coordinate Cr(iii)-chloro species react cleanly with sodium azide to form the corresponding azido species, which undergo photolysis under irradiation at 419
R I Arunkumar et al.
Fish & shellfish immunology, 10(8), 667-676 (2001-02-24)
The objective of this study was to investigate the effect of trivalent (chromic chloride) and hexavalent (potassium dichromate) forms of chromium in the African mouth breeder Oreochromis mossambicus (Peters), with reference to the humoral immune response and lymphoid cells/organs. The
Olivia J Phung et al.
American journal of health-system pharmacy : AJHP : official journal of the American Society of Health-System Pharmacists, 67(7), 535-541 (2010-03-20)
The effect of i.v. chromium administration on glucose control in two patients receiving enteral nutrition is described. Chromium supplementation has been hypothesized to potentiate the actions of insulin in facilitating cellular uptake of glucose. We report two cases-one involving a
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