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Differential conductance (dI/dV) imaging of a heterojunction-nanorod.

Nanotechnology (2017-01-31)
Biswajit Kundu, Abhijit Bera, Amlan J Pal
RÉSUMÉ

Through scanning tunneling spectroscopy, we envisage imaging a heterostructure, namely a junction formed in a single nanorod. While the differential conductance spectrum provides location of conduction and valence band edges, dI/dV images record energy levels of materials. Such dI/dV images at different voltages allowed us to view p- and n-sections of heterojunction nanorods and more importantly the depletion region in such a junction that has a type-II band alignment. Viewing of selective sections in a heterojunction occurred due to band-bending in the junction and is correlated to the density of states spectrum of the individual semiconductors. The dI/dV images recorded at different voltages could be used to generate a band diagram of a pn junction.

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Sigma-Aldrich
Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 97%
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Tributylphosphine solution, 200 mM (in N-methyl-2-pyrrolidinone), liquid