Induced circular dichroism of stereoregular vinyl polymers.

Induced circular dichroism of stereoregular vinyl polymers.

Chemical communications (Cambridge, England) (2012-03-08)

Lung-Chi Chen, Yung-Cheng Mao, Shih-Chieh Lin, Ming-Chia Li, Rong-Ming Ho, Jing-Cherng Tsai

RÉSUMÉ

Stereoregular vinyl polymers, poly(2-vinyl pyridine)s (P2VPs), were synthesized to examine the tacticity effect on the induced circular dichroism (ICD) via association with chiral acids. The ICD was found to be strongly dependent on the isotacticity of the P2VPs and the acidity of chiral acid in addition to its bulkiness.

MATÉRIAUX

Référence du produit

Marque

Description du produit

523321

Supelco

Poly(2-vinylpyridine), analytical standard, average M_w 37,500 (Typical), average M_n 35,000 (Typical)

523356

Supelco

Poly(2-vinylpyridine), analytical standard, average M_w 159,000 (Typical), average M_n 152,000 (Typical)