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Extended Le Chatelier's formula for carbon dioxide dilution effect on flammability limits.

Journal of hazardous materials (2006-06-20)
Shigeo Kondo, Kenji Takizawa, Akifumi Takahashi, Kazuaki Tokuhashi
RÉSUMÉ

Carbon dioxide dilution effect on the flammability limits was measured for various flammable gases. The obtained values were analyzed using the extended Le Chatelier's formula developed in a previous study. As a result, it has been found that the flammability limits of methane, propane, propylene, methyl formate, and 1,1-difluoroethane are adequately explained by the extended Le Chatelier's formula using a common set of parameter values. Ethylene, dimethyl ether, and ammonia behave differently from these compounds. The present result is very consistent with what was obtained in the case of nitrogen dilution.

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Sigma-Aldrich
Methyl formate, anhydrous, 99%
Sigma-Aldrich
Methyl formate, reagent grade, 97%
Sigma-Aldrich
Methyl formate, spectrophotometric grade, ≥98%
Supelco
Methyl formate, analytical standard