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Merck

Development of a green binder system for paper products.

BMC biotechnology (2013-03-28)
Ashley R Flory, Deborah Vicuna Requesens, Shivakumar P Devaiah, Keat Thomas Teoh, Shawn D Mansfield, Elizabeth E Hood
ABSTRACT

It is important for industries to find green chemistries for manufacturing their products that have utility, are cost-effective and that protect the environment. The paper industry is no exception. Renewable resources derived from plant components could be an excellent substitute for the chemicals that are currently used as paper binders. Air laid pressed paper products that are typically used in wet wipes must be bound together so they can resist mechanical tearing during storage and use. The binders must be strong but cost-effective. Although chemical binders are approved by the Environmental Protection Agency, the public is demanding products with lower carbon footprints and that are derived from renewable sources. In this project, carbohydrates, proteins and phenolic compounds were applied to air laid, pressed paper products in order to identify potential renewable green binders that are as strong as the current commercial binders, while being organic and renewable. Each potential green binder was applied to several filter paper strips and tested for strength in the direction perpendicular to the cellulose fibril orientation. Out of the twenty binders surveyed, soy protein, gelatin, zein protein, pectin and Salix lignin provided comparable strength results to a currently employed chemical binder. These organic and renewable binders can be purchased in large quantities at low cost, require minimal reaction time and do not form viscous solutions that would clog sprayers, characteristics that make them attractive to the non-woven paper industry. As with any new process, a large-scale trial must be conducted along with an economic analysis of the procedure. However, because multiple examples of "green" binders were found that showed strong cross-linking activity, a candidate for commercial application will likely be found.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Gelatin, tested according to Ph. Eur.
Sigma-Aldrich
Gelatin from bovine skin, gel strength ~225 g Bloom, Type B
Sigma-Aldrich
Gelatin from bovine skin, Type B
Sigma-Aldrich
Pectin from citrus peel, Galacturonic acid ≥74.0 % (dried basis)
Sigma-Aldrich
Gelatin from porcine skin, Type A, lyophilized powder, γ-irradiated, BioXtra, suitable for cell culture
Sigma-Aldrich
Gelatin from porcine skin, powder, gel strength ~300 g Bloom, Type A, BioReagent, suitable for electrophoresis, suitable for cell culture
Sigma-Aldrich
Zein
Sigma-Aldrich
Gelatin from cold water fish skin, solid
Millipore
Gelatin from porcine skin, medium gel strength, suitable for microbiology
Sigma-Aldrich
Prionex® Highly purified Type A, aqueous solution
Sigma-Aldrich
Gelatin from porcine skin, gel strength 80-120 g Bloom, Type A
Sigma-Aldrich
Gelatin from porcine skin, gel strength ~175 g Bloom, Type A
Sigma-Aldrich
Gelatin from porcine skin, gel strength 300, Type A
Sigma-Aldrich
Gelatin solution, Type B, 2% in H2O, tissue culture grade, BioReagent, suitable for cell culture
Supelco
Pectin, for use with Total Dietary Fiber Control Kit, TDF-C10
Millipore
Gelatin from porcine skin, suitable for microbiology, high gel strength
Sigma-Aldrich
Gelatin from bovine skin, Type B, powder, BioReagent, suitable for cell culture
Millipore
Gelatin from porcine skin, suitable for microbiology, low gel strength
Millipore
Gelatin from porcine skin, suitable for microbiology, ultrahigh gel strength