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  • Direct aerobic photo-oxidative synthesis of aromatic methyl esters from methyl aromatics via dimethyl acetals.

Direct aerobic photo-oxidative synthesis of aromatic methyl esters from methyl aromatics via dimethyl acetals.

Organic letters (2010-07-31)
Shin-Ichi Hirashima, Tomoya Nobuta, Norihiro Tada, Tsuyoshi Miura, Akichika Itoh
ZUSAMMENFASSUNG

A useful method for facile synthesis of aromatic methyl esters from methyl aromatics via dimethyl acetals by aerobic photo-oxidation using inexpensive and easily handled CBr(4) as catalyst is reported. This is the first example for direct preparation of the corresponding aromatic methyl esters from methyl aromatics.

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

Sigma-Aldrich
Acetaldehyddimethylacetal, 95%
Sigma-Aldrich
1,1-Dimethoxyethan, ≥97%, FG