681792

N-tert-Butylbenzolsulfenamid

97%

• Synonym(e): 2-Methyl-N-(phenylthio)-propan-2-amin, N-(1,1-Dimethylethyl)-benzolsulfenamid
• Empirische Formel (Hill-System): C₁₀H₁₅NS
• CAS-Nummer: 19117-31-8
• Molekulargewicht: 181.30
• MDL-Nummer: MFCD03844776
• UNSPSC-Code: 12352002
• PubChem Substanz-ID: 24885655
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Eignung der Reaktion: reagent type: oxidant
• Brechungsindex: n20/D 1.5457
• bp: 57-60 °C/0.3 mmHg
• Dichte: 0.997 g/mL at 25 °C
• SMILES String: CC(C)(C)NSc1ccccc1
• InChI: 1S/C10H15NS/c1-10(2,3)11-12-9-7-5-4-6-8-9/h4-8,11H,1-3H3
• InChIKey: AAQBFMPKCDTAJD-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Anti-SN2′ Mitsunobu reaction with chiral hydroxy-alpha-alkenylsilanes to give vinylsilanes
• Anodic oxidation reactions

In the presence of NCS, this sulfenamide catalyzes the mild and selective oxidation of primary and secondary alcohols to the respective aldehydes and ketones.

Sicherheitshinweise

• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 205.0 °F - closed cup
• Flammpunkt (°C): 96.11 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)