414247

2-Methyltetrahydrofuran

BioRenewable, anhydrous, ≥99.0%, contains 250 ppm BHT as stabilizer

• Synonyme(s) : Tétrahydro-2-méthylfurane
• Formule empirique (notation de Hill): C₅H₁₀O
• Numéro CAS: 96-47-9
• Poids moléculaire : 86.13
• Numéro Beilstein : 102448
• Numéro CE : 202-507-4
• Numéro MDL: MFCD00005367
• Code UNSPSC : 12352005
• ID de substance PubChem : 57650057
• Nomenclature NACRES : NA.07

Propriétés

• Qualité: anhydrous
• Niveau de qualité: 100
• Pureté: ≥99.0%
• Forme: liquid
• Contient: 250 ppm BHT as stabilizer
• Limite d'explosivité: 0.34-6.3 %
• Caractéristiques du produit alternatif plus écologique: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Impuretés: <0.002% water; <0.005% water (100 mL pkg)
• Résidus d'évap.: <0.0003%
• Indice de réfraction: n20/D 1.406 (lit.)
• Point d'ébullition: 78-80 °C (lit.)
• Pf: -136 °C
• Densité: 0.86 g/mL at 25 °C (lit.)
• Autre catégorie plus écologique: Aligned, , Aligned
• Chaîne SMILES: CC1CCCO1
• InChI: 1S/C5H10O/c1-5-3-2-4-6-5/h5H,2-4H2,1H3
• Clé InChI: JWUJQDFVADABEY-UHFFFAOYSA-N

Description

Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is a biorenewable and thus aligns with "Safer Solvents and Auxiliaries" and "Use of Renewable Feedstocks". Click here for more information.
2-Methyltetrahydrofuran (2-MTHF), a 2-methyl substituted tetrahdrofuran, is a biomass derived solvent. It is a potential greener solvent alternative for organic synthesis. It shows resistance to reduction by lithium making it a promising candidate as electrolytes in lithium batteries. Its polarity and Lewis base strength is intermediate between tetrahydrofuran (THF) and diethyl ether. The ring opening reaction of 2-MTHF has been studied using acid chloride and iodide to form secondary chlorides and primary iodides respectively. On long term storage, tetrahydrofuran forms organic peroxides. This process can be suppressed by adding butylated hydroxytoluene (BHT) as a stabilizer. BHT removes the free radicals required for the peroxide formation.

Application

2-Methyltetrahydrofuran may be used as solvent for phosphatidylserine synthesis.
It may be used as an alternative solvent to:

• DMSO (dimethyl sulfoxide) or MTBE (methyl tertiary butyl ether) in the C-C bond forming reactions catalyzed by lyase enzyme.
• THF in the reaction between Grignard reagents and carbonyl compounds.
• Methylene chloride in some biphase reactions.

Green Alternatives to DCM and THF from Renewable Resources

Organic Solar Cells

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Caractéristiques et avantages

Greener alternative for THF, DCM, DMSO, and MTBE

Conditionnement

View returnable container options.

Autres remarques

Pure-Pac^® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.

Informations légales

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

Informations sur la sécurité

• Pictogrammes: GHS02,GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H225,H302,H315,H318
• Conseils de prudence: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2
• Risques supp: EUH019
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): 14.0 °F - closed cup
• Point d'éclair (°C): -10.0 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter