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Key Documents

939315

Sigma-Aldrich

Copper(II) sulfate pentahydrate

new

≥99.9% (trace metals basis)

Synonyme(s) :

Blue Vitriol, Cupric sulfate pentahydrate

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About This Item

Formule empirique (notation de Hill):
CuSO4. 5H2O
Code UNSPSC :
12352302
Code UNSPSC :
51211624

Pression de vapeur

7.3 mmHg ( 25 °C)

Niveau de qualité

Type

(High purity Salts)

Pureté

≥99.9% (trace metals basis)
98-102% (Titration by Na2S2O3)

Forme

powder or crystals

Impuretés

<1000 ppm (total metallic impurities)

Couleur

faint blue to very dark blue

Pf

110 °C (lit.)

Solubilité

water: soluble

Traces d'anions

chloride (Cl-): ≤20 ppm

Traces de cations

Al: <50 ppm
Cu: <50 ppm
Fe: <50  ppm
K: <50 ppm
Mg: <50 ppm
Na: <50 ppm
Pb: <50 ppm
Zn: <50 ppm

Application(s)

battery manufacturing

Température de stockage

room temp

Description générale

Copper(II) sulfate pentahydrate is a blue colored crytal known as blue vitrol. It is highly soluble in water and methanol whereas it is insluble in ethanol and acetone. Copper(II) sulfate pentahydrate is commonly used in various applications such as agriculture, electroplating, and as a laboratory reagent. It is widely use in developing low-cost and efficient electrocatalysts for applications such as water splitting, which is essential for the production of hydrogen as a clean fuel.

Application

  • Copper(II) sulfate pentahydrate can be used as a precursor
  • To synthesis of Molecular organic framwork (MOF) with benzene-1,3,5-tricarboxylic acid via solvothermal synthesis. This metal-organic framework (MOF) used as a heterogeneous catalyst for the biodiesel production with high yield
  • To synthesis of Ni foam film-supported CoCu alloy microspheres composed of nanosheets which act as a catalyst for the hydrolysis of ammonia borane. The catalyst has exhibited stability and reuseability.
  • Copper(II) sulfate pentahydrate can be used as a catalyst:
  • In acetylation of alcohols and phenols in the presence of acetic anhydride.
  • Many different copper-based compounds have been studied as catalysts in Copper-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) using Cu(II) species such as Copper sulphate pentahydrate.
  • Catalyst for the synthesis of macrocyclic ynamides via intramolecular amidation of alkynyl Bromides.
  • It can also be used as a template in the synthesis of copper(II) ion-imprinted polymers using vinylpyridine and methacrylic acid as functional monomers. This polymer is used to quantify Cu2+ ion by using flame atomic absorption spectroscopy.

Caractéristiques et avantages

  • Medium purity with trace metals basis
  • Inexpensive
  • Safe catalyst
  • Reuseability is high

Pictogrammes

CorrosionExclamation markEnvironment

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Copper(II)-catalyzed amidations of alkynyl bromides as a general synthesis of ynamides and Z-enamides. An intramolecular amidation for the synthesis of macrocyclic ynamides
Zhang X, et al.
The Journal of Organic Chemistry, 71(11), 4170-7 (2006)
Electromagnetic-field-assisted synthesis of Ni foam film-supported CoCu alloy microspheres composed of nanosheets: A high performance catalyst for the hydrolysis of ammonia borane
Liao J, et al.
Catalysis Communications, 122, 16- 19 (2019)
The synthesis of biodiesel using copper based metal-organic framework as a catalyst
Pangestu T, et al.
Journal of Environmental Chemical Engineering, 7, 103277-103277 (2019)
Copper(I)-Catalyzed Alkyne?Azide Cycloaddition (CuAAC) ?Click? Reaction: A Powerful Tool for Functionalizing Polyhydroxylated Platforms
Pineda-Casta?eda H M, et al.
ACS Omega, 8(4), 3650?3666-3650?3666 (2023)

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