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905100

Sigma-Aldrich

Ir(p-tBu-ppy)3

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About This Item

Formule empirique (notation de Hill):
C45H48IrN3
Numéro CAS:
1396451-04-9
Poids moléculaire :
823.10
Code UNSPSC :
12352101
Nomenclature NACRES :
NA.22

Forme

powder

Capacité de réaction

reaction type: Photocatalysis

Pertinence de la réaction

reagent type: catalyst

Catégories apparentées

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

688096

Tris[2-phenylpyridinato-C2,N]iridium(III), 97%

900540

Ir(dFppy)3

900539

Ir[p-F(t-Bu)-ppy]3

900538

Ir(p-F-ppy)3

900570

Ir[dF(t-Bu)-ppy]3

904694

Ir(p-CF3-ppy)3, ≥95%

905097

Ir(p-Me-ppy)3

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Certificats d'analyse (COA)

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Xiao-Jing Wei et al.
ACS catalysis, 7(10), 7136-7140 (2017-11-08)
The development of synthetic methodologies which provide access to both stereoisomers of α,β-disubstituted olefins is a challenging undertaking. Herein, we describe the development of an operationally simple and stereoselective synthesis of difluoromethylated styrenes via a visible-light photocatalytic decarboxylation strategy using
Eric D Nacsa et al.
Journal of the American Chemical Society, 140(9), 3322-3330 (2018-02-06)
Nature routinely engages alcohols as leaving groups, as DNA biosynthesis relies on the removal of water from ribonucleoside diphosphates by a radical-mediated "spin-center shift" (SCS) mechanism. Alcohols, however, remain underused as alkylating agents in synthetic chemistry due to their low
Amandeep Arora et al.
Organic letters, 18(16), 3996-3999 (2016-08-06)
The 2-azolyl radical, generated from 2-bromoazoles via photocatalysis, is a powerful intermediate for the intermolecular arylation of unmodified (hetero)arenes. The reaction is characterized by mild conditions, operational simplicity, tolerance toward functional and sterically demanding groups, broad scope, and anti-Minisci selectivity.
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh A, et al.
Journal of Organometallic Chemistry, 776, 51-59 (2015)

Contenu apparenté

Weaver Group – Professor Product Portal

Organofluorine chemistry is an essential part of drug discovery programs as well as agrochemical programs and even plays a major role in materials chemistry. Despite the undeniable importance of fluorinated organic molecules, our ability to synthesize these substrates is lacking - though arguably it is better than that of Nature. Consequently, methods that allow facile access to fluorinated molecules are important especially when they provide unique access to fluorinated chemical space.

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