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359009

Sigma-Aldrich

Cerium(IV) sulfate

Synonyme(s) :

Ceric sulfate, Cerium disulfate

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About This Item

Formule linéaire :
Ce(SO4)2
Numéro CAS:
13590-82-4
Poids moléculaire :
332.24
Numéro CE :
237-029-5
Numéro MDL:
MFCD00148852
Code UNSPSC :
12161600
ID de substance PubChem :
24862046
Nomenclature NACRES :
NA.22

Forme

powder

Niveau de qualité

100

Pertinence de la réaction

core: cerium
reagent type: catalyst

Densité

3.01 g/mL at 25 °C (lit.)

Chaîne SMILES 

[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4

Clé InChI

VZDYWEUILIUIDF-UHFFFAOYSA-J

Application

Cerium(IV) sulfate can be used to catalyze:
  • Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant.
  • Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid.
  • Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions.

Reactant for:
  • Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions

  • Oxidizing agent

Autres remarques

may contain excess sulfate

Pictogrammes

CorrosionEnvironment
GHS05,GHS09

Mention d'avertissement

Danger

Mentions de danger

H314,H410

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Code de la classe de stockage

8B - Non-combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves

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Amarinder Singh et al.
Toxicology and applied pharmacology, 318, 8-15 (2017-01-26)
The limiting factor for the use of Cisplatin in the treatment of different type of cancers is its toxicity and more specifically urogenital toxicity. Oxidative stress is a well-known phenomenon associated with Cisplatin toxicity. However, in Cisplatin treated group, abnormal
Ju Peng Wang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(1), 204-208 (2008-02-05)
A simple, sensitive and rapid flow-injection chemiluminescence method has been developed for the determination of ferulic acid based on the chemiluminescence reaction of ferulic acid with rhodamine 6G and ceric sulfate in sulphuric acid medium. Strong chemiluminescence signal was observed
Radamés Alvarez-Zapata et al.
Journal of chromatography. A, 1422, 213-221 (2015-10-31)
This work describes the use of Colubrina greggii as a model to investigate the use of chemometric analysis combined with data from a leishmanicidal bioassay, using Principal Component Analysis (PCA) and Orthogonal Projections to Latent Structures (O-PLS), to detect biologically
J Bello-Martínez et al.
Pharmacognosy magazine, 13(Suppl 2), S289-S293 (2017-08-16)
The aim of this study was to isolate the compounds responsible for antiproliferative activity of A bioassay-guided fractionation of ethanol extract of The flavonoid brazilin (1) was isolated from the heartwood of Brazilin: (6a The flavonoid brazilin was isolated from
Ochuko L Erukainure et al.
Frontiers in pharmacology, 9, 8-8 (2018-02-17)
Type 2 diabetes is the most prominent of all diabetes types, contributing to global morbidity and mortality. Availability and cost of treatment with little or no side effect especially in developing countries, remains a huge burden. This has led to
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