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203491

Sigma-Aldrich

Iridium(III) chloride hydrate

99.9% trace metals basis

Synonyme(s) :

Iridium trichloride hydrate

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About This Item

Formule linéaire :
IrCl3 · xH2O
Numéro CAS:
14996-61-3
Poids moléculaire :
298.58 (anhydrous basis)
Numéro CE :
233-044-6
Numéro MDL:
MFCD00149749
Code UNSPSC :
12352302
ID de substance PubChem :
24852176
Nomenclature NACRES :
NA.23

Niveau de qualité

100

Pureté

99.9% trace metals basis

Forme

crystals and lumps

Pertinence de la réaction

reagent type: catalyst
core: iridium

Impuretés

≤1500.0 ppm Trace Metal Analysis

Densité

5.3 g/mL at 25 °C (lit.)

Chaîne SMILES 

[H]O[H].Cl[Ir](Cl)Cl

InChI

1S/3ClH.Ir.H2O/h3*1H;;1H2/q;;;+3;/p-3

Clé InChI

MJRFDVWKTFJAPF-UHFFFAOYSA-K

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Description générale

Iridium(III) chloride hydrate is a dark green to black hygroscopic solid that is widely used as a Ir source/precursor to synthesize Ir nanoparticle and battery materials.

Application

Iridium(III) chloride hydrate can be used:
  • As a precursor to synthesize IrO2 nanofibrous catalyst for oxygen evolution reaction.
  • As a starting material to prepare Ir complex that acts as an additive to hole transport layer in perovskite solar cells. This Ir complex helps to reduce recombination rate and enhances the stability of solar cells.
  • To fabricate thin and highly active IrO2 anodes for proton exchange membrane electrolyzer cells (PEMECs).
  • As a precursor to synthesize ionic Ir metal complexes for efficient flexible green light-emitting electrochemical cells. This leads to enhanced quantum efficiency and luminescence.

Pictogrammes

Exclamation mark
GHS07

Mention d'avertissement

Warning

Mentions de danger

H319

Conseils de prudence

P305 + P351 + P338

Classification des risques

Eye Irrit. 2

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves

Certificats d'analyse (COA)

Recherchez un Certificats d'analyse (COA) en saisissant le numéro de lot du produit. Les numéros de lot figurent sur l'étiquette du produit après les mots "Lot" ou "Batch".

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Consulter la Bibliothèque de documents

Shaped Ir?Ni bimetallic nanoparticles for minimizing Ir utilization in oxygen evolution reaction.
Lim J,et al.
Chemical Communications (Cambridge, England), 52(32), 5641-5644 (2016)
Maximilian Moser et al.
Angewandte Chemie (International ed. in English), 53(33), 8628-8633 (2014-06-04)
Rutile TiO2 is a heavily investigated oxide with, to date, scarce applications in industrial catalysis. The inactivity of this material in oxidations has been related to its inability to dissociate molecular oxygen. Herein we show how rutile catalyzes the oxidation
Ann M Rajnicek et al.
Advanced healthcare materials, 7(17), e1800473-e1800473 (2018-07-06)
Innovative neurostimulation therapies require improved electrode materials, such as poly(3,4-ethylenedioxythiophene) (PEDOT) polymers or IrOx mixed ionic-electronic conductors and better understanding of how their electrochemistry influences nerve growth. Amphibian neurons growing on transparent films of electronic (metal) conductors and electronic-ionic conductors
Ultrabright oxygen optodes based on cyclometalated iridium (III) coumarin complexes.
Borisov SM and Klimant I
Analytical Chemistry, 79(19), 7501-7509 (2007)

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