913154

1,10-Phenanthroline nickel (ll) dibromide

• Synonym(s): (phen)NiBr₂
• Empirical Formula (Hill Notation): C₁₂H₈Br₂N₂Ni
• CAS Number: 48165-50-0
• Molecular Weight: 398.71
• UNSPSC Code: 12352200
• NACRES: NA.22

Properties

• form: powder
• Quality Level: 100
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings
• SMILES string: Br[Ni]1(Br)[N]2=CC=CC3=C2C([N]1=CC=C4)=C4C=C3

Description

Application

1,10-Phenanthroline nickel (ll) dibromide is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols.

Other Notes

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3