540129

(2S)-(+)-Glycidyl tosylate

98%

• Synonym(s): (S)-(+)-Glycidyl p-toluenesulfonate, (S)-(+)-Oxirane-2-methanol p-toluenesulfonate
• Empirical Formula (Hill Notation): C₁₀H₁₂O₄S
• CAS Number: 70987-78-9
• Molecular Weight: 228.26
• Beilstein: 3592143
• EC Number: 417-210-7
• MDL number: MFCD00064489
• UNSPSC Code: 12352005
• PubChem Substance ID: 24878443
• NACRES: NA.22

Properties

• Assay: 98%
• mp: 46-49 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: Cc1ccc(cc1)S(=O)(=O)OC[C@@H]2CO2
• InChI: 1S/C10H12O4S/c1-8-2-4-10(5-3-8)15(11,12)14-7-9-6-13-9/h2-5,9H,6-7H2,1H3/t9-/m0/s1
• InChI key: NOQXXYIGRPAZJC-VIFPVBQESA-N

Description

Application

Used in the first enantioselective synthesis of (R)- and (S)-4-acetyl-3-(hydroxymethyl)-3,4-dihydro-2H-pyrido[3,2-b]oxazines.

Legal Information

Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.

Safety Information

• Pictograms: GHS08,GHS05,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H317,H318,H341,H350,H411
• Precautionary Statements: P201 - P273 - P280 - P302 + P352 - P305 + P351 + P338 + P310 - P308 + P313
• Hazard Classifications: Aquatic Chronic 2 - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Sens. 1
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): 235.4 °F - closed cup
• Flash Point(C): 113 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves