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Key Documents

337048

Sigma-Aldrich

2,2-Dimethyl-1-phenyl-1-propanol

99%

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About This Item

Linear Formula:
(CH3)3CCH(C6H5)OH
CAS Number:
Molecular Weight:
164.24
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

bp

90 °C/5 mmHg (lit.)

mp

43-45 °C (lit.)

SMILES string

CC(C)(C)C(O)c1ccccc1

InChI

1S/C11H16O/c1-11(2,3)10(12)9-7-5-4-6-8-9/h4-8,10,12H,1-3H3

InChI key

YBVRFTBNIZWMSK-UHFFFAOYSA-N

General description

Raney nickel and Raney cobalt catalyzed transfer hydrogenolysis of 2,2-dimethyl-1-phenyl-1-propanol has been reported. Kinetic resolution of 2,2-dimethyl-1-phenyl-1-propanol using a lead dioxide anode modified with poly-S-valine grafted on to a polypyrrole film has been reported. An efficient Cu(I)-catalyzed oxidation of 2,2-dimethyl-1-phenyl-1-propanol with di-tert-butyldiaziridinone as oxidant under mild conditions has been investigated.

Application

2,2-Dimethyl-1-phenyl-1-propanol was used in the preparation of 2,2-dimethylpropiophenone.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

206.6 °F - closed cup

Flash Point(C)

97.00 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Transfer hydrogenolysis of aromatic alcohols using Raney catalysts and 2-propanol.
Gross BH, et al.
Applied Catalysis A: General, 219(1), 281-289 (2001)
Brant Landers et al.
The Journal of organic chemistry, 76(5), 1390-1397 (2011-01-22)
The use of commercially available (SIPr)Pd(cinnamyl)Cl (SIPr = 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene) as a precatalyst for the anaerobic oxidation of secondary alcohols is described. The use of this complex allows for a drastic reduction in the reaction times and catalyst loading when compared
Poly (pyrroles) containing chiral side chains: effect of substituents on the chiral recognition in the doped as well as in the undoped state of the polymer film.
Pleus S and Schulte B.
Journal of Solid State Electrochemistry, 5(7-8), 522-520 (2001)
Yingguang Zhu et al.
Organic letters, 15(5), 992-995 (2013-02-19)
A novel and efficient Cu(I)-catalyzed oxidation of alcohols has been achieved with di-tert-butyldiaziridinone as the oxidant under mild conditions. A wide variety of primary and secondary alcohols with various functional groups can be oxidized to aldehydes and ketones in high

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