- C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents.
C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents.
Chemical communications (Cambridge, England) (2002-10-26)
Nathalie Merceron, Antoine Baceiredo, Heinz Gornitzka, Guy Bertrand
PMID12398001
RÉSUMÉ
C-Phosphanyl-C-chloroiminium salts formally react as phosphonio(amino)carbenes with tert-butyl isocyanide and trimethylphosphine, and as R2NC+ with vinyl ether and diisopropylamine.
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