Solvent- and Catalyst-Free Carbon Dioxide Capture and Reduction to Formate with Borohydride Ionic Liquid.

The metal- and solvent-free capture and reduction of large amounts of CO2 to formate under ambient conditions is achieved by combining a pyrrolidinium-based ionic liquid with a borohydride anion. This material demonstrates one of the highest CO2 capacities at room temperature and 1 bar with up to 1 g CO 2  g-1IL . CO2 gas reacts with the BH4- anion to give triformatoborohydride, [HB(OCHO)3 ]- . The reaction occurs without loss in capacity at low CO2 concentration (6 vol % diluted with N2 ). The thermodynamics and kinetics of the reaction were monitored by using a magnetic suspended balance. In addition, more than 1 mol CO 2  mol-1 [ EMPY ] [ BH 4 ] is captured and reduced if air is used as a CO2 source. The product can be then treated with HCl to give formic acid and the corresponding ionic liquid chloride, which can be recycled. This ionic liquid borohydride demonstrates great potential as a CO2 absorber and reducer to produce alternative fuels.