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940119

Sigma-Aldrich

Copper(I) Chloride ChemBeads

new

15 wt% loading

Synonyme(s) :

Copper monochloride ChemBeads, CuCl ChemBeads, Cuprous chloride ChemBeads

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About This Item

Formule empirique (notation de Hill):
CuCl
Numéro CAS:
Poids moléculaire :
99.00
Numéro MDL:
Code UNSPSC :
12352100

Forme

solid

Niveau de qualité

Composition

15 wt% loading

Pertinence de la réaction

reagent type: catalyst

Chaîne SMILES 

[Cu+].[Cl-]

Description générale

Copper(I) chloride is a lewis acid and a useful source of copper(I) in chemical synthesis. Loaded on glass beads for use in high-throughput expermentation (HTE).

Application

Copper(I) chloride (Cuprous chloride, CuCl) has been used: In the synthesis of 7-((tert-butyldimethylsilyl)oxy)hepta-2,4-diyn-1-ol.
In the synthesis of CuInSe nanocrystals.
To catalyze the synthesis of benzothiazolethiones from iodoanilines, isocyanide and potassium sulfide.
Shows unique character as an initiator of radical reactions such as the hydrostannation of α,β-unsaturated ketones.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

For general uses, product is also available in powdered form (212946)

Produit(s) apparenté(s)

Pictogrammes

CorrosionEnvironment

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Beeraiah Baire et al.
Nature protocols, 8(3), 501-508 (2013-02-16)
The hexadehydro-Diels-Alder (HDDA) cascade enables the synthesis of complex benzenoid products with various substitution patterns through aryne intermediates. The first stage of this cascade involves the generation of a highly reactive ortho-benzyne intermediate by a net [4+2] cycloisomerization of a
Bryan T Ingoglia et al.
Tetrahedron, 75(32), 4199-4211 (2020-01-04)
Over the past three decades, Pd-catalyzed cross-coupling reactions have become a mainstay of organic synthesis. In particular, catalysts derived from biaryl monophosphines have shown wide utility in forming C-N bonds under mild reaction conditions. This work summarizes a variety of
Bonil Koo et al.
Journal of the American Chemical Society, 131(9), 3134-3135 (2009-02-17)
The synthesis of monodisperse chalcopyrite (tetragonal) CuInSe(2) nanocrystals is reported. The nanocrystals have trigonal pyramidal shape, and they exhibited a common crystallographic orientation when drop-cast onto carbon substrates. A crystallographic model for the nanocrystals was developed. The nanocrystals are bounded
Ana L Aguirre et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(51), 12981-12986 (2021-07-08)
High-throughput experimentation (HTE) methods are central to modern medicinal chemistry. While many HTE approaches to C-N and Csp2 -Csp2 bonds are available, options for Csp2 -Csp3 bonds are limited. We report here how the adaptation of nickel-catalyzed cross-electrophile coupling of
Noah P Tu et al.
Angewandte Chemie (International ed. in English), 58(24), 7987-7991 (2019-03-21)
Technologies that enable rapid screening of diverse reaction conditions are of critical importance to methodology development and reaction optimization, especially when molecules of high complexity and scarcity are involved. The lack of a general solid dispensing method for chemical reagents

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