733210

Tetrakis(dimethylsulfoxide)dichlororuthenium(II)

96%

• Synonyme(s) : Dichlorotetrakis(dimethyl sulfoxide)ruthenium
• Formule empirique (notation de Hill): C₈H₂₄Cl₂O₄RuS₄
• Numéro CAS: 89395-66-4
• Poids moléculaire : 484.51
• Code UNSPSC : 12161600
• ID de substance PubChem : 329764798
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: 96%
• Forme: solid
• Pertinence de la réaction: core: ruthenium; reagent type: catalyst
• Pf: 192-198 °C
• Chaîne SMILES: O=S(C)C.O=S(C)C.Cl[Ru](Cl)O=S(C)C.O=S(C)C
• InChI: 1S/4C2H6OS.2ClH.Ru/c4*1-4(2)3;;;/h4*1-2H3;2*1H;/q;;;;;;+2/p-2
• Clé InChI: UMJDEUKQHKMAOI-UHFFFAOYSA-L

Description

Description générale

Tetrakis(dimethylsulfoxide)dichlororuthenium(II), [RuCl₂(dmso)₄] is an organoruthenium compound. It is used as a homogeneous catalyst in organic synthesis.

Tetrakis(dimethylsulfoxide)dichlororuthenium(II) (Ru(DMSO)4Cl2) is a coordination complex generally used as a catalyst in various reactions. In addition, it is also used as a precursor in the synthesis of other ruthenium complexes.

Application

RuCl₂(dmso)₄ can be used as a catalyst for:

• The β-alkylation of secondary alcohols via hydrogen auto-transfer process.
• The oxidation of thioethers (S) to sulfoxides by N-methylmorpholine N-oxide (NMO).

Tetrakis(dimethylsulfoxide)dichlororuthenium(II) can be used as a precursor in the synthesis of Ru(II)-MEPE (metallo-supramolecular polyelectrolytes) complex, which is used to prepare electrochromic organic-metallic hybrid polymers.

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable