661023

Hydroxy(cyclooctadiene)rhodium(I) dimer

95%

• Synonyme(s) : (Cyclooctadiene)rhodium hydroxide dimer, 1,5-Cyclooctadiene)hydroxyrhodium dimer, Bis(cyclooctadiene)dihydroxodirhodium, Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di--μ-hydroxydirhodium, Bis[(1,5-cyclooctadiene)(hydroxy)rhodium], [Rh(OH)(1,5-cod)]₂
• Formule empirique (notation de Hill): C₁₆H₂₆O₂Rh₂
• Numéro CAS: 73468-85-6
• Poids moléculaire : 456.19
• Numéro MDL: MFCD08457638
• Code UNSPSC : 12161600
• ID de substance PubChem : 24884496
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: 95%
• Forme: solid
• Pertinence de la réaction: core: rhodium; reagent type: catalyst
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Pf: 199 °C (dec.)
• Autre catégorie plus écologique: Aligned,
• Chaîne SMILES: O[Rh].O[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.2H2O.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H2;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
• Clé InChI: IUAQXTGDGDIMOD-MIXQCLKLSA-L

Description

Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Efficient and Selective Catalysts for Asymmetric Synthesis

Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Rhodium catalyst employed with R-BINAP or R-SEGPHOS^® ligands in a synthesis of chiral 3,3-disubstituted-1-indanones.

Informations légales

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)