357537

Pentamethylcyclopentadienyliridium(III) chloride,dimer

96%

• Synonyme(s) : di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-iridium
• Formule empirique (notation de Hill): C₂₀H₃₀Cl₄Ir₂
• Numéro CAS: 12354-84-6
• Poids moléculaire : 796.70
• Numéro MDL: MFCD00075435
• Code UNSPSC : 12161600
• ID de substance PubChem : 24861924
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: 96%
• Forme: solid
• Pertinence de la réaction: core: iridium; reagent type: catalyst
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Autre catégorie plus écologique: Aligned,
• Chaîne SMILES: Cl[Ir]Cl.Cl[Ir]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
• InChI: 1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
• Clé InChI: JDOHSXHCQARCAW-UHFFFAOYSA-J

Description

Description générale

Pentamethylcyclopentadienyliridium(III) chloride, dimer is utilized as a catalyst in cross-coupling and dimerization reactions.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for greener amine synthesis from amines and alcohols by hydrogen-borrowing. Precursor to cooperative metal-Bronsted acid catalyst for greener reductive amination using hydrogen gas.

Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Development of GSK's reagent guides – embedding sustainability into reagent selection

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)