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303070

Sigma-Aldrich

Methyl pentafluorobenzoate

99%

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About This Item

Formule linéaire :
C6F5CO2CH3
Numéro CAS:
36629-42-2
Poids moléculaire :
226.10
Numéro MDL:
MFCD00012172
Code UNSPSC :
12352100
ID de substance PubChem :
24858294
Nomenclature NACRES :
NA.22

Pureté

99%

Forme

liquid

Indice de réfraction

n20/D 1.431 (lit.)

Densité

1.532 g/mL at 25 °C (lit.)

Chaîne SMILES 

COC(=O)c1c(F)c(F)c(F)c(F)c1F

InChI

1S/C8H3F5O2/c1-15-8(14)2-3(9)5(11)7(13)6(12)4(2)10/h1H3

Clé InChI

UXJRQNXHCZKHRJ-UHFFFAOYSA-N

Catégories apparentées

Application

Methyl pentafluorobenzoate was used in preparation of photocoupling agent, based on perfluorophenylazide (PFPA)-conjugated polyallylamine, for efficient immobilization of polymers, nanoparticles, graphene and small molecules. It was also used in preparation of photoactive reagent N-hydroxysuccinimide (NHS)-PFPA.

Pictogrammes

Exclamation mark
GHS07

Mention d'avertissement

Warning

Mentions de danger

H315,H319,H335

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

10 - Combustible liquids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

172.4 °F - closed cup

Point d'éclair (°C)

78 °C - closed cup

Équipement de protection individuelle

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificats d'analyse (COA)

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Takuya Kubo et al.
Langmuir : the ACS journal of surfaces and colloids, 27(15), 9372-9378 (2011-06-28)
A highly efficient photocoupling agent, based on perfluorophenylazide (PFPA)-conjugated polyallylamine (PAAm), was developed for the efficient immobilization of polymers, nanoparticles, graphene, and small molecules. The conjugate, PAAm-PFPA, was synthesized, and the percentage of the photoactive moiety, PFPA, can be controlled
Huibin Wang et al.
Bioconjugate chemistry, 22(1), 26-32 (2010-12-09)
A universal photochemical method has been established for the immobilization of intact carbohydrates and their analogues, and for the fabrication of carbohydrate microarrays. The method features the use of perfluorophenyl azide (PFPA)-modified substrates and the photochemical reaction of surface azido
Hiroshi Kobayashi et al.
Scientific reports, 10(1), 13850-13850 (2020-08-17)
We report on a potential method to separate sugars by using the specific interaction between fullerenes and saccharides in liquid chromatography (LC). Aromatic rings with high electron density are believed to interact strongly with saccharides due to CH-π and/or OH-π
Marllyn Marques da Silva et al.
Regulatory toxicology and pharmacology : RTP, 103, 282-291 (2019-02-23)
The fibrinolytic enzyme produced by Mucor subtilissimus UCP 1262 was obtained by solid fermentation and purified by ion exchange chromatography using DEAE-Sephadex A50. The enzyme toxicity was evaluated using mammalian cell lineages: HEK-293, J774.A1, Sarcoma-180 and PBMCs which appeared to
Na Kong et al.
Carbohydrate research, 405, 33-38 (2015-03-10)
Carbohydrate-functionalized single-walled carbon nanotubes (SWNTs) were synthesized using microwave-assisted reaction of perfluorophenyl azide with the nanotubes. The results showed that microwave radiation provides a rapid and effective means to covalently attach carbohydrates to SWNTs, producing carbohydrate-SWNT conjugates for biorecognition. The

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