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Sigma-Aldrich

Ruthenium(III) chloride hydrate

ReagentPlus®

Synonyme(s) :

Ruthenium trichloride

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About This Item

Formule linéaire :
RuCl3 · xH2O
Numéro CAS:
14898-67-0
Poids moléculaire :
207.43 (anhydrous basis)
Numéro CE :
233-167-5
Numéro MDL:
MFCD00149844
Code UNSPSC :
12352302
ID de substance PubChem :
24852386
Nomenclature NACRES :
NA.23

Niveau de qualité

200

Gamme de produits

ReagentPlus®

Forme

powder and chunks

Composition

Degree of hydration, ≤1
Ruthenium content, 40.00-49.00%

Pertinence de la réaction

reagent type: catalyst
core: ruthenium

Impuretés

≤0.1% Insoluble matter (C=1%, 25% HCl)

Chaîne SMILES 

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

Clé InChI

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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Description générale

Ruthenium(III) chloride hydrate ReagentPlus® is a versatile and valuable compound in various scientific and industrial applications, particularly due to its catalytic properties and role in material science. Its ability to participate in numerous chemical reactions and processes makes it an essential reagent in both research and practical applications. It comes with black or grey color with insoluble matter ≤ 0.1 %; and % Ruthenium after reduction with Magnesium is 40.00 - 49.00 %.

Application

Ruthenium(III) chloride hydrate (RuCl₃·xH₂O) is a versatile compound with several applications across different fields. It can be used as a catalyst hydrogeneation, oxidation reachtions. For example, one of the study has found it as an efficient catalyst for the selective oxidation of fatty alcohols to aldehydes. Due to its excellent conductivity and ability to withstand higher temperature, the product is used in electronics as a precursor for thin film deposition. Thin films of ruthenium and its derivatives are used in the fabrication of memory devices, microelectromechanical systems (MEMS) and integrated circuits. It can be used in the preparation of electrodes for electrochemical cells due to its good conductivity and stability. Ruthenium(III) chloride hydrate is used in the synthesis of ruthenium nanoparticles, which have applications in catalysis, electronics, and material science. Ruthenium compounds are being researched for their potential use as anticancer agents due to their ability to bind to DNA and inhibit cell proliferation. In addition, ruthenium(III) chloride hydrate is utilized in the field of solar energy. It is used as a sensitizer in dye-sensitized solar cells (DSSCs). DSSCs are an alternative to traditional silicon-based photovoltaic cells with low cost and easy fabrication process. Ruthenium-based dyes absorb light and transfer electrons, initiating the energy conversion process in DSSCs.

Caractéristiques et avantages

Ruthenium(III) Chloride hydrate ReagentPlus® has been designed and tested keeping the requirements of research applications with low insoluble matters, specifications ensuring the material is suitable for high-performance applications and provides consistency in experimental and industrial processes.

Informations légales

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

CorrosionExclamation markEnvironment
GHS05,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H302,H314,H411

Classification des risques

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificats d'analyse (COA)

Recherchez un Certificats d'analyse (COA) en saisissant le numéro de lot du produit. Les numéros de lot figurent sur l'étiquette du produit après les mots "Lot" ou "Batch".

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Consulter la Bibliothèque de documents

TiO 2 nanotube-supported ruthenium (III) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen.
Bavykin DV, et al.
J. Catal., 235(1), 10-17 (2005)
Synthesis of ruthenium complexes and their catalytic applications: A review
Hafeez J, et al.
Arabian Journal of Chemistry, 15, 104165-104165 (2022)
Ruthenium(III) Chloride as an Efficient Catalyst for the Selective Oxidation of Fatty Alcohols to Aldehydes
Nunheim F N, et al.
ChemistrySelect, 8, e202300346-e202300346 (2023)
Meser M Ali et al.
Journal of nanomedicine & nanotechnology, 10(6), 35248/2157-35248/7439 (2020-01-30)
Dye-sensitized solar cells (DSSCs) have attracted enormous attention in the last couple of decades due to their relatively small size, low cost and minimal environmental impact. DSSCs convert solar energy to electrical energy with the aid of a sensitizing dye.
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
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