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201146

Sigma-Aldrich

Lithium hexafluorophosphate

98%

Synonyme(s) :

Lithium phosphorus fluoride

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About This Item

Formule linéaire :
LiPF6
Numéro CAS:
21324-40-3
Poids moléculaire :
151.91
Numéro CE :
244-334-7
Numéro MDL:
MFCD00011096
Code UNSPSC :
12352302
ID de substance PubChem :
24851997
Nomenclature NACRES :
NA.23

Pureté

98%

Forme

powder

Pf

200 °C (dec.) (lit.)

Solubilité

H2O: slightly soluble(lit.)

Densité

1.5 g/mL (lit.)

Chaîne SMILES 

[Li+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

Clé InChI

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Lithium hexafluorophosphate is an electrolyte salt widely used in lithium-ion batteries.

Caractéristiques et avantages

  • It can form suitable SEI membranes in electrodes, especially in the cathode
  • It can implement passivation for anode current collectors to prevent their dissolution
  • Wide windows of electrical stability
  • Excellent solubility and high conductivity in various solvents
  • Environment-friendly

Pictogrammes

Skull and crossbonesHealth hazardCorrosion
GHS06,GHS08,GHS05

Mention d'avertissement

Danger

Mentions de danger

H301,H314,H372

Classification des risques

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation

Organes cibles

Bone,Teeth

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

M D S Lekgoathi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 153, 651-654 (2015-10-11)
The structure of LiPF6 has been probed using Raman scattering as well as pXRD and the results are compared and contrasted. The conventional Bragg angle scattering pXRD determines that dry LiPF6 crystallizes in a trigonal structure (Space Group R-3 (148))
Kewei Liu et al.
ACS nano, 9(6), 6041-6049 (2015-06-06)
The two-dimensional single-layer and few-layered graphene exhibit many attractive properties such as large specific surface area and high charge carrier mobility. However, graphene sheets tend to stack together and form aggregates, which do not possess the desirable properties associated with
Shijia Zhao et al.
Nanoscale, 7(5), 1984-1993 (2014-12-30)
Hydrogenated carbon nanomaterials exhibit many advantages in both mechanical and electrochemical properties, and thus have a wide range of potential applications. However, methods to control the hydrogenation and the effect of hydrogenation on the microstructure and properties of the produced
Jiangfeng Qian et al.
Nature communications, 6, 6362-6362 (2015-02-24)
Lithium metal is an ideal battery anode. However, dendrite growth and limited Coulombic efficiency during cycling have prevented its practical application in rechargeable batteries. Herein, we report that the use of highly concentrated electrolytes composed of ether solvents and the

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