201073

Aluminum-tri-sec-butoxide

97%

• Synonyme(s) : Aluminum sec-butoxide
• Formule linéaire : Al[OCH(CH₃)C₂H₅]₃
• Numéro CAS: 2269-22-9
• Poids moléculaire : 246.32
• Numéro Beilstein : 3910908
• Numéro CE : 218-871-2
• Numéro MDL: MFCD00009327
• Code UNSPSC : 12352103
• ID de substance PubChem : 24851994
• Nomenclature NACRES : NA.23

Propriétés

• Niveau de qualité: 100
• Pureté: 97%
• Forme: liquid
• Température d'inflammation spontanée: 763 °F
• Limite d'explosivité: 9.8 %
• Pertinence de la réaction: core: aluminum
• Point d'ébullition: 200-206 °C/30 mmHg (lit.)
• Densité: 0.967 g/mL at 25 °C (lit.)
• Chaîne SMILES: CCC(C)O[Al](OC(C)CC)OC(C)CC
• InChI: 1S/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3
• Clé InChI: WOZZOSDBXABUFO-UHFFFAOYSA-N

Description

Description générale

Aluminum-tri-sec-butoxide is a metal organic chemical vapor deposition precursor and a chelating agent. It is widely used as a sol-gel precursor to deposit alumina thin films by atomic layer deposition method.

Application

Aluminum-tri-sec-butoxide can be used as a precursor :

• To prepare Al₂O₃-based quasi-solid electrolyte for Li metal anodes. This ensures long cycle lifetime and high constant current density.
• To synthesize nanospinel MgAl₂O₄ powder by a sol–gel method at low-temperature processing.
• To fabricate transparent superhydrophobic aluminum oxide thin films to prevent soiling of solar panels.
• To synthesize mesoporous alumina with large surface area to fabricate a functional interlayer for separator coating in a Li–S battery. It helps to suppress the shuttle effect and enhances cyclic stability andrateperformance.

Caractéristiques et avantages

• Suitable for thin film deposition
• Solubility in various solvents allows for the facile preparation of solution-based precursors
• High thermal stability
• Facilitates the anchoring of catalytic metal nanoparticles onto substrates

Has been utilized in making high-surface-area alumina using 2,4-pentanedione (Aldrich product P775-4) as a chelating agent.

Informations sur la sécurité

• Pictogrammes: GHS02,GHS06
• Mention d'avertissement: Danger
• Mentions de danger: H226,H302,H311
• Conseils de prudence: P210 - P233 - P240 - P280 - P301 + P312 - P303 + P361 + P353
• Classification des risques: Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): 78.8 °F - closed cup
• Point d'éclair (°C): 26 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter