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Reactivity of the parent amido complexes of iridium with olefins: C-NH

Dalton transactions (Cambridge, England : 2003) (2017-08-19)
Inmaculada Mena, Pilar García-Orduña, Víctor Polo, Fernando J Lahoz, Miguel A Casado, Luis A Oro
RÉSUMÉ

Herein we report on the different chemical reactivity displayed by two mononuclear terminal amido compounds depending on the nature of the coordinated diene. Hence, treatment of amido-bridged iridium complexes [{Ir(μ-NH

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1,3-Bis(diphenylphosphino)propane, 97%
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1,4-Bis(diphenylphosphino)butane, 98%