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Cobalt Schiff-base complexes for electrocatalytic hydrogen generation.

Dalton transactions (Cambridge, England : 2003) (2017-07-27)
Ryan J DiRisio, Jessica E Armstrong, Mariah A Frank, William R Lake, William R McNamara
RÉSUMÉ

Two cobalt(iii) complexes containing inexpensive Schiff-base ligands have been found to be active for proton reduction at low overpotentials. The dinitro and tetranitro derivatized Schiff-base complexes show catalytic activity at -0.96 V and -1.1 V vs. Fc

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2-Hydroxy-5-nitrobenzaldehyde, 98%