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1-Methyl-1H-benzimidazole-2(3H)-thione.

Acta crystallographica. Section E, Structure reports online (2008-01-01)
Hizbullah Khan, Amin Badshah, Farkhanda Shaheen, Christine Gieck, Rizwana Aleem Qureshi
RÉSUMÉ

The title compound, C(8)H(8)N(2)S, was prepared by the condensation of N-methyl-1,2-phenyl-enediamine and carbon disulfide. The crystal structure is stabilized by a C-H⋯π inter-action between a benzene H atom and the benzene ring of a neighbouring mol-ecule, and by inter-molecular N-H⋯S inter-actions.

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Sigma-Aldrich
N-Methyl-1,2-phenylenediamine, 97%