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Parallel synthesis of 1,2,4-oxadiazoles using CDI activation.

Bioorganic & medicinal chemistry letters (1999-02-18)
T L Deegan, T J Nitz, D Cebzanov, D E Pufko, J A Porco
RÉSUMÉ

1,2,4-Oxadiazoles have been prepared in parallel using 1,1'-carbonyldiimidazole (CDI) as a reagent for both formation and cyclodehydration of O-acyl benzamidoximes. The use of CDI facilitates parallel purification of the oxadiazole products by simple liquid-liquid extraction and filtration.

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Benzamide oxime, 97%