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Preparation of alkylidene indane and related scaffolds and their further elaboration to novel chemotypes.

Organic letters (2007-11-14)
Sarathy Kesavan, James S Panek, John A Porco
RÉSUMÉ

Alkylidene indane and ring-expanded scaffolds have been prepared using an enantioselective crotylation/Heck cyclization sequence. Further diversification using consecutive cyclopropanation-Cope rearrangement affords novel chemotypes including spiroindane frameworks.

MATÉRIAUX
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Description du produit

Sigma-Aldrich
Indan, 95%
Supelco
Indan, analytical standard