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  • Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C-C and C-N bonds.

Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C-C and C-N bonds.

Chemical communications (Cambridge, England) (2012-02-15)
Rajarshi Samanta, Jonas Lategahn, Andrey P Antonchick
ABSTRACT

A new atom-economical process of direct oxidative intermolecular functionalization of aniline derivatives by simple arenes was developed. The products were formed in a highly regioselective manner under metal-free conditions at ambient temperature.

MATERIALS
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Brand
Product Description

Sigma-Aldrich
1-tert-Butyl-3,5-dimethylbenzene, 98%