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37310

Sigma-Aldrich

5,6-Dihydro-4-methoxy-2H-pyran

technical, ≥85% (GC)

Synonym(s):

4-Methoxy-5,6-dihydropyran

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About This Item

Empirical Formula (Hill Notation):
C6H10O2
CAS Number:
Molecular Weight:
114.14
Beilstein:
1341205
EC Number:
MDL number:
UNSPSC Code:
12352100

grade

technical

Assay

≥85% (GC)

refractive index

n20/D 1.462 (lit.)
n20/D 1.463

bp

59 °C/20 mmHg (lit.)

density

1.022 g/mL at 25 °C (lit.)

SMILES string

COC1=CCOCC1

InChI

1S/C6H10O2/c1-7-6-2-4-8-5-3-6/h2H,3-5H2,1H3

InChI key

FSMHNRHLQAABPS-UHFFFAOYSA-N

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Caution

may discolor to deep yellow on storage

Other Notes

Reagent used for the introduction of the achiral Mthp protecting group for alcohols; derivatization does not introduce an asymmetric center, used primarily in oligonucleotide synthesis

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D.G. Norman et al.
Synthesis, 874-874 (1985)
4-methoxytetrahydropyran-4-yl. A symmetrical alternative to the tetrahydropyranyl protecting group.
C B Reese et al.
Tetrahedron, 26(4), 1023-1030 (1970-02-01)

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