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Key Documents

738689

Sigma-Aldrich

Cyanomethyl methyl(4-pyridyl)carbamodithioate

98%

Synonym(s):

S-Cyanomethyl-N-methyl-N-(pyridin-4-yl)dithiocarbamate

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About This Item

Empirical Formula (Hill Notation):
C9H9N3S2
CAS Number:
Molecular Weight:
223.32
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.23

Assay

98%

form

solid

mp

129-132 °C
3652-3697 °C (lit.)

storage temp.

2-8°C

SMILES string

CN(C(=S)SCC#N)c1ccncc1

InChI

1S/C9H9N3S2/c1-12(9(13)14-7-4-10)8-2-5-11-6-3-8/h2-3,5-6H,7H2,1H3

InChI key

URLWWHOJXDIKQC-UHFFFAOYSA-N

Application

Switchable RAFT agent for controlled radical polymerization. The neutral form is well-suited for polymerization of vinyl esters and vinyl amides (LAMs), and the protonated form is well-suited for styrenes acrylates and methacrylates (MAMs). Chain Transfer Agent (CTA)

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Skin Sens. 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Articles

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocols

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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