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Key Documents

677876

Sigma-Aldrich

Trichloro(pyridine)gold(III)

97%

Synonym(s):

(Pyridine)gold trichloride

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About This Item

Empirical Formula (Hill Notation):
C5H5AuCl3N
CAS Number:
Molecular Weight:
382.43
MDL number:
UNSPSC Code:
12352300
eCl@ss:
39151701
PubChem Substance ID:

Assay

97%

reaction suitability

core: gold
reagent type: catalyst

mp

232-240 °C

SMILES string

Cl[Au](Cl)Cl.c1ccncc1

InChI

1S/C5H5N.Au.3ClH/c1-2-4-6-5-3-1;;;;/h1-5H;;3*1H/q;+3;;;/p-3

InChI key

TYJJOEBQRJABJG-UHFFFAOYSA-K

Application

Gold Catalysts — 21st Century ′Gold Rush′

  • An N-stabilized gold(III) catalyst employed in a synthesis of tetrahydroisoquinolines.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Gold catalysis: the benefits of N and N,O ligands.
A Stephen K Hashmi et al.
Angewandte Chemie (International ed. in English), 43(47), 6545-6547 (2004-12-04)

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