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510033

Sigma-Aldrich

Raney®-Nickel

W.R. Grace and Co. Raney® 2400, slurry, in H2O, active catalyst

Synonym(s):

Raney Ni, Nickel sponge

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About This Item

Linear Formula:
AlNi
CAS Number:
7440-02-0
MDL number:
MFCD00167392
UNSPSC Code:
12161600
PubChem Substance ID:
24873469
NACRES:
NA.22

form

slurry

reaction suitability

core: nickel
reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 2400

concentration

in H2O

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

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Application

Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

Signal Word

Danger

Hazard Statements

H250,H317,H351,H372

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A J Feilzer et al.
Nederlands tijdschrift voor tandheelkunde, 120(6), 335-341 (2013-07-19)
Orally applied metal alloys can cause undesirable physical effects. A distinction needs to be made in this respect between local and systemic reactions and toxic and immunological reactions. A case is presented which illustrates this problem. In this case, the
Fariborz Amini et al.
International journal of orthodontics (Milwaukee, Wis.), 24(1), 43-44 (2013-06-05)
In this report, we present an uncomplicated approach to overcome lingual rolling of mandibular molars during orthodontic treatment, by using rectangular NiTi arch wire in twist fashion through the molar tube. The sequential steps of the twist manoeuvre on a
Palatally anchored maxillary molar mesialization using the mesialslider.
Benedict Wilmes et al.
Journal of clinical orthodontics : JCO, 47(3), 172-179 (2013-05-11)
Picture of the month. Allergic contact dermatitis to nickel-containing dental work.
Emma F Johnson et al.
JAMA pediatrics, 167(6), 581-582 (2013-06-05)
Marilia O S Seijo et al.
Journal of dental education, 77(5), 648-655 (2013-05-10)
Including students' perceptions in the educational process is considered a key component in monitoring the quality of academic programs. This study aimed to evaluate the concept of one's learning experience in endodontic teaching from the perspective of a group of
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Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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