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Merck

Recent advances in homogeneous nickel catalysis.

Nature (2014-05-16)
Sarah Z Tasker, Eric A Standley, Timothy F Jamison
ABSTRACT

Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions. In recent years, these properties have been increasingly understood and used to perform transformations long considered exceptionally challenging. Here we discuss some of the most recent and significant developments in homogeneous nickel catalysis, with an emphasis on both synthetic outcome and mechanism.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis
Sigma-Aldrich
Nickel, powder, <50 μm, 99.7% trace metals basis
Sigma-Aldrich
Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis
Sigma-Aldrich
Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis
Sigma-Aldrich
Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis
Sigma-Aldrich
Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis
Nickel, foil, 4mm disks, thickness 0.5mm, annealed, 99.98%
Nickel, foil, 4mm disks, thickness 0.20mm, annealed, 99%
Nickel, foil, 5m coil, thickness 0.075mm, annealed, 99%
Nickel, foil, 50mm disks, thickness 0.25mm, annealed, 99%
Nickel, foil, 50mm disks, thickness 0.01mm, 99.95%
Nickel, foil, 50mm disks, thickness 0.125mm, as rolled, 99.99+%
Nickel, foil, 4mm disks, thickness 0.25mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.50mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.075mm, annealed, 99%
Nickel, foil, 5m coil, thickness 0.025mm, annealed, 99%
Nickel, foil, 4mm disks, thickness 0.25mm, as rolled, 100%
Nickel, foil, 50mm disks, thickness 0.075mm, as rolled, 99.98%
Nickel, foil, 50mm disks, thickness 0.25mm, as rolled, 99.99+%
Nickel, foil, 5m coil, thickness 0.0125mm, 99.9%
Nickel, foil, 5m coil, thickness 0.15mm, coil width 12mm, annealed, 99%
Nickel, foil, 50mm disks, thickness 0.025mm, annealed, 99%
Nickel, foil, 50mm disks, thickness 0.038mm, 99.9%
Nickel, foil, 50mm disks, thickness 0.025mm, 99.9%
Nickel, foil, 4mm disks, thickness 0.125mm, as rolled, 100%
Nickel, foil, 50mm disks, thickness 0.03mm, 99.9%
Nickel, foil, 5m coil, thickness 0.05mm, annealed, 99%
Nickel, foil, 50mm disks, thickness 0.0125mm, 99.99+%
Nickel, foil, 50mm disks, thickness 0.0025mm, 99.95%
Nickel, foil, 4mm disks, thickness 0.3mm, as rolled, 100%