- A substrate-unspecified glycosylation reaction promoted by copper(II) trifluoromethanesulfonate in benzotrifluoride.
A substrate-unspecified glycosylation reaction promoted by copper(II) trifluoromethanesulfonate in benzotrifluoride.
Carbohydrate research (2002-03-23)
Hidetoshi Yamada, Tomomi Hayashi
PMID11909590
ABSTRACT
A glycosylation reaction induced by copper(II) trifluoromethanesulfonate is described. Using benzotrifluoride as the reaction solvent, five kinds of glycosyl donors, a glucosyl chloride, a fluoride, a trichloroacetimidate, a 1-O-acetyl compound, and a lactol were activated to give the corresponding glucosides.
MATERIALS
Product Number
Brand
Product Description
Sigma-Aldrich
α,α,α-Trifluorotoluene solution, NMR reference standard, 0.05% in benzene-d6 (99.6 atom % D)
Sigma-Aldrich
α,α,α-Trifluorotoluene solution, NMR reference standard, 0.05% in benzene-d6 (99.6 atom % D), NMR tube size 3 mm × 8 in.
Sigma-Aldrich
α,α,α-Trifluorotoluene solution, NMR reference standard, 0.05% in benzene-d6 (99.6 atom % D), NMR tube size 10 mm × 8 in.