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Vinyl diazophosphonates as precursors to quaternary substituted indolines and cyclopentenes.

Organic letters (2011-01-18)
Jin Wang, Vyacheslav Boyarskikh, Jon D Rainier
RESUMO

Vinyl diazophosphonates can be stereoselectively synthesized and, depending upon their substitution pattern, undergo intramolecular C-H insertion reactions or sulfonium ylide rearrangements when exposed to Rh(2)(OAc)(4).

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Sigma-Aldrich
Rhodium(II) acetate dimer, powder
Sigma-Aldrich
Rhodium(II) acetate dimer, 99.9% trace metals basis