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  • A metal-organic framework with a covalently prefabricated porous organic linker.

A metal-organic framework with a covalently prefabricated porous organic linker.

Journal of the American Chemical Society (2010-08-28)
Shashikala I Swamy, John Bacsa, James T A Jones, Kyriakos C Stylianou, Alexander Steiner, Lyndsey K Ritchie, Tom Hasell, Jamie A Gould, Andrea Laybourn, Yaroslav Z Khimyak, Dave J Adams, Matthew J Rosseinsky, Andrew I Cooper
PMID20795723
ABSTRACT

We report here the synthesis of a metal-organic framework comprising an organic cage linker with covalently prefabricated, intrinsic porosity. The network can be compared to a porous rock salt structure where the pores are partially filled by charge-balancing cations.