- Oxidative cleavage of allyl ethers by an oxoammonium salt.
Oxidative cleavage of allyl ethers by an oxoammonium salt.
Organic & biomolecular chemistry (2015-03-10)
Christopher B Kelly, John M Ovian, Robin M Cywar, Taylor R Gosselin, Rebecca J Wiles, Nicholas E Leadbeater
PMID25748071
ABSTRACT
A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.
MATERIALS
Product Number
Brand
Product Description
Sigma-Aldrich
4-(Acetylamino)-2,2,6,6-tetramethyl-1-oxo-piperidinium tetrafluoroborate, 97% (HPLC)