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  • Monitoring of the 17 EU Watch List contaminants of emerging concern in the Ave and the Sousa Rivers.

Monitoring of the 17 EU Watch List contaminants of emerging concern in the Ave and the Sousa Rivers.

The Science of the total environment (2018-10-13)
João C G Sousa, Ana R Ribeiro, Marta O Barbosa, Cláudia Ribeiro, Maria E Tiritan, M Fernando R Pereira, Adrián M T Silva
ABSTRACT

The occurrence of micropollutants in the environment is a matter of high concern. Some regulations have been published in the last years and a Watch List of contaminants of emerging concern (CECs) for European Union monitoring of surface water was launched in the Decision 2015/495, including three estrogens (estrone, E1; 17-β-estradiol, E2; and 17-α-ethinylestradiol, EE2), four pharmaceuticals (diclofenac and the macrolide antibiotics azithromycin, clarithromycin and erythromycin), an anti-oxidant (2,6-ditert-butyl-4-methylphenol, BHT), an UV filter (2-ethylhexyl 4-methoxycinnamate, EHMC), some pesticides (methiocarb and the neonicotinoids imidacloprid, thiacloprid, thiamethoxam, clothianidin and acetamiprid) and two herbicides (oxadiazon and triallate). This study provides the first spatial and seasonal monitoring campaign in the Ave and the Sousa Rivers for the all set of the 17 Watch List CECs (not reported yet for any country), in order to assess their occurrence, distribution, frequency and risk assessment. It also highlights the need of extend the study to other regions and environmental matrices to investigate the occurrence and possible sources of contamination of CECs, aiming to give insights for decision makers to define mitigation strategies for a more sustainable water policy.

MATERIALS
Product Number
Brand
Product Description

Supelco
Clothianidin-d3, PESTANAL®, analytical standard
Pricing and availability is not currently available.
Supelco
Clothianidin, PESTANAL®, analytical standard
Pricing and availability is not currently available.
Sigma-Aldrich
Azithromycin dihydrate, ≥98% (HPLC)
Pricing and availability is not currently available.
Supelco
Thiamethoxam, PESTANAL®, analytical standard
Pricing and availability is not currently available.
Supelco
N-(6-Chloro-3-pyridylmethyl)-N-cyano-N-methylacetamidine, PESTANAL®, analytical standard
Pricing and availability is not currently available.
Sigma-Aldrich
21-Hydroxyprogesterone, ≥97% (HPLC)
Pricing and availability is not currently available.
Supelco
Oxadiazon, PESTANAL®, analytical standard
Pricing and availability is not currently available.
Sigma-Aldrich
Ethyl acetate, anhydrous, 99.8%
Pricing and availability is not currently available.
Sigma-Aldrich
Pyridine, anhydrous, 99.8%
Pricing and availability is not currently available.
Supelco
Methiocarb, PESTANAL®, analytical standard
Pricing and availability is not currently available.
Supelco
Acetamiprid-d3, PESTANAL®, analytical standard
Pricing and availability is not currently available.
Supelco
Thiacloprid, PESTANAL®, analytical standard
Pricing and availability is not currently available.