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Tetradodecylammonium tetrakis(4-chlorophenyl)borate

Selectophore

Synonym(s):

ETH 500, Tetrakis(4-chlorophenyl)borate tetradodecylammonium salt

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About This Item

Empirical Formula (Hill Notation):
C72H116BCl4N
CAS Number:
Molecular Weight:
1148.32
Beilstein:
8894894
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NB.61

grade

for ion-selective electrodes

Quality Level

product line

Selectophore

form

powder

mp

79-80 °C

SMILES string

Clc1ccc(cc1)[B-](c2ccc(Cl)cc2)(c3ccc(Cl)cc3)c4ccc(Cl)cc4.CCCCCCCCCCCC[N+](CCCCCCCCCCCC)(CCCCCCCCCCCC)CCCCCCCCCCCC

InChI

1S/C48H100N.C24H16BCl4/c1-5-9-13-17-21-25-29-33-37-41-45-49(46-42-38-34-30-26-22-18-14-10-6-2,47-43-39-35-31-27-23-19-15-11-7-3)48-44-40-36-32-28-24-20-16-12-8-4;26-21-9-1-17(2-10-21)25(18-3-11-22(27)12-4-18,19-5-13-23(28)14-6-19)20-7-15-24(29)16-8-20/h5-48H2,1-4H3;1-16H/q+1;-1

InChI key

OKKRVCFTMNLHTL-UHFFFAOYSA-N

General description

ETH 500 is a lipophilic electrolyte mostly used as an anionic additive.
Visit our Sensor Applications portal to learn more.

Application

ETH 500 has been used in the preparation of:
  • molecularly imprinted polymers, which can be used during potentiometric sensing method for determining neutral phenols.
  • copolymer Ca2+ selective membrane cocktail during electrochemical impedance spectroscopic analysis to study the water intake and layer formation in ion-selective electrode.

Other Notes

Highly lipophilic additive for membranes of neutral carrier-based ion-selective macroelectrodes; Additive in membranes of optodes

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Lipophilic and immobilized anionic additives in solvent polymeric membranes of cation-selective chemical sensors.
Rosatzin, Thomas, et al.
Analytica Chimica Acta, 280.2, 197-208 (1993)
D. Ammann et al.
Analytica Chimica Acta, 171, 119-119 (1985)
Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor.
Kou LJ
Analytical and Bioanalytical Chemistry, 405(14), 4931-4936 (2013)
Eduardo Laborda et al.
Angewandte Chemie (International ed. in English), 56(3), 782-785 (2016-12-10)
A new electrochemical framework for tracking individual soft particles in solution and monitoring their fusion with polarized liquid-liquid interfaces is reported. The physicochemical principle lies in the interfacial transfer of an ionic probe confined in the particles dispersed in solution
W.E. Morf et al.
Pure and Applied Chemistry. Chimie Pure Et Appliquee, 61, 1613-1613 (1989)

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