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Sigma-Aldrich

Chromium(II) chloride

AnhydroBeads™, −10 mesh, 99.99% trace metals basis

Synonym(s):

Chromium dichloride, Chromous chloride

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About This Item

Linear Formula:
CrCl2
CAS Number:
10049-05-5
Molecular Weight:
122.90
EC Number:
233-163-3
MDL number:
MFCD00010947
UNSPSC Code:
12352302
PubChem Substance ID:
329767009
NACRES:
NA.23

product line

AnhydroBeads™

Assay

99.99% trace metals basis

form

beads

impurities

≤150.0 ppm Trace Metal Analysis

particle size

−10 mesh

mp

824 °C (lit.)

density

2.9 g/mL at 25 °C (lit.)

SMILES string

Cl[Cr]Cl

InChI

1S/2ClH.Cr/h2*1H;/q;;+2/p-2

InChI key

XBWRJSSJWDOUSJ-UHFFFAOYSA-L

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Application

Anhydrous chromium chloride is an important precursor for the low temperature synthesis of anhydrous metal sulfides, nitrides, phosphides, etc. It is also an important precursor for the synthesis of chromium containing mixed metal complexes; example lithium chromium chloride (Li2CrCl4), which shows rapid lithium ion conduction.

Anhydrous chromium chloride finds applications as catalysts, chromizing ferrous metals, steel, etc. The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.

Chromium chloride powder is air and water sensitive. Beads have lower surface area and pour easily.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Precautionary Statements

P301 + P312 + P330

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Liliana Viciu et al.
Inorganic chemistry, 41(13), 3385-3388 (2002-06-25)
A new series of transition-metal oxyhalides (MCl)LaNb(2)O(7) (M = Cr, Mn, Fe, Co) have been prepared by a simple topochemical route. Layered perovskite hosts (ALaNb(2)O(7), A = Li, Na, K or Rb) were reacted with the corresponding anhydrous metal halides
Martin, M. J.; et al.
Inorganic Chemistry, 27, 2804-2804 (1988)
Mohammad Mehdi Moeini et al.
Biological trace element research, 144(1-3), 715-724 (2011-06-22)
A total of 250 broilers in a completely randomized design selected to evaluate the effect of different levels of chromium (Cr) supplementation on performance, carcass traits and some blood parameters of heat-stressed broiler chicks. All birds were kept under heat
Mehdi Toghyani et al.
Biological trace element research, 146(2), 171-180 (2011-10-19)
This study was conducted to determine the effects of dietary supplementation with Cr nicotinate and Cr chloride and their optimum inclusion rate on performance, carcass traits, meat oxidative stability, serum metabolites, hematological parameters, and liver chromium concentration in heat-stressed broilers.
K Anastaze Stelle et al.
Pediatric transplantation, 16(3), 250-256 (2011-12-20)
The aim of this study was to analyze the impact of TAC on medium term (three-yr follow-up) renal function in pediatric liver transplant (OLT) recipients. Glomerular and tubular indices were retrospectively analyzed in 24 consecutive OLT pediatric recipients on TAC.
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