11630
2,2′-Azobis(2-methylpropionitrile)
purum, ≥98.0% (GC)
Synonym(s):
α,α′-Azoisobutyronitrile, AIBN, Azobisisobutyronitrile, Free radical initiator
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About This Item
Linear Formula:
(CH3)2C(CN)N=NC(CH3)2CN
CAS Number:
Molecular Weight:
164.21
Beilstein:
1708400
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
grade
purum
Quality Level
Assay
≥98.0% (GC)
form
solid
impurities
≤2% water
ign. residue
≤0.1%
mp
102-104 °C (dec.) (lit.)
storage temp.
2-8°C
SMILES string
CC(C)(\N=N\C(C)(C)C#N)C#N
InChI
1S/C8H12N4/c1-7(2,5-9)11-12-8(3,4)6-10/h1-4H3/b12-11+
InChI key
OZAIFHULBGXAKX-VAWYXSNFSA-N
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General description
Radical initiator
Application
- Polymer Chemistry: Analysis of polymer synthesis using AIBN under various conditions, with emphasis on thermal initiation properties (Suriyanarayanan & Nicholls, 2019).
- Influence of cyclodextrin on the UCST-and LCST-behavior of poly (2-methacrylamido-caprolactam)-co-(N, N-dimethylacrylamide): Explores the role of AIBN in copolymerization processes influencing polymer properties relevant to material science applications (Burkhart & Ritter, 2014).
- Preparation and characterization of polyaniline microcapsule loaded with 2, 2′‐azobis (2‐methylpropionitrile) initiator and its controlled release: Demonstrates innovative applications of AIBN in microencapsulation techniques, targeting enhanced performance in adhesive industries (Zhang et al., 2022).
Storage and Stability
Warning: these products are subject to the Explosives Act and must be transported refrigerated - additional costs for transport will apply.
Other Notes
Sales restrictions may apply
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Self-react. C
Supplementary Hazards
Storage Class Code
4.1A - Other explosive hazardous materials
WGK
WGK 2
Flash Point(F)
122.0 °F
Flash Point(C)
50 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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In the presence of a catalytic amount of radical initiator AIBN, primary amines are oxidatively coupled to imines and tertiary amines are cyanated to α-aminonitriles. These "metal-free" aerobic oxidative coupling reactions may find applications in a wide range of "green"
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