Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

538647

Sigma-Aldrich

1-Fluorododecane

98%

Synonym(s):

n-Dodecyl fluoride

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
F(CH2)11CH3
CAS Number:
334-68-9
Molecular Weight:
188.33
EC Number:
206-381-1
MDL number:
MFCD00013580
UNSPSC Code:
12352100
PubChem Substance ID:
24878349
NACRES:
NA.22

Assay

98%

refractive index

n20/D 1.42 (lit.)

density

0.807 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCCCF

InChI

1S/C12H25F/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3

InChI key

YHYBNVZCQIDLSQ-UHFFFAOYSA-N

General description

1-Fluorododecane is a long chain 1-fluoroalkane. It can be synthesized from the reaction between 1-dodecanol, N,N-diethyl-α,α-difluoro-[3,5-bis(1H,1H,2H,2H-perfluorodecyl)benzyl]amine and heptane. 1-Fluorododecane undergoes reaction with dibromomethane and titanocene dichloride in the presence of triethyl aluminium (Et3Al) to afford a mixture of 1-chlorododecane and 1-bromododecane. 1-Fluorododecane can also be prepared from 1-hydroxydodecane.

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H300,H413

Precautionary Statements

P273 - P301 + P310 + P330

Hazard Classifications

Acute Tox. 2 Oral - Aquatic Chronic 4

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

223.0 °F - closed cup

Flash Point(C)

106.1 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Regioselective Hydroxylation of C12?C15 Fatty Acids with Fluorinated Substituents by Cytochrome P450 BM3.
Chiang, Chih-Hsiang, et al.
Chemistry?A European Journal , 19(41), 13680-13691 (2013)
Fluorination of alcohols and diols with a novel fluorous deoxy-fluorination reagent.
Furuya T, et al.
Journal of Fluorine Chemistry, 130(2), 348-353 (2009)
Vapor Pressures and Boiling Points of the 1-Fluoroalkanes, 1-Chloroalkanes, 1-Bromoalkanes, and 1-Iodoalkanes, C1to C20.
Li JCM and Rossini RD.
Journal of Chemical and Engineering Data, 6(2), 268-270 (1961)
Halogen Exchange Reaction of Aliphatic Fluorine Compounds with Organic Halides as Halogen Source.
Mizukami Y, et al.
Organic Letters, 17(24), 5942-5945 (2015)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service