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129259

Sigma-Aldrich

2,3-Dimethyl-2-butene

98%

Synonym(s):

Tetramethylethylene

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About This Item

Linear Formula:
(CH3)2C=C(CH3)2
CAS Number:
563-79-1
Molecular Weight:
84.16
Beilstein:
1361357
EC Number:
209-263-8
MDL number:
MFCD00008897
UNSPSC Code:
12352100
PubChem Substance ID:
24847892
NACRES:
NA.22

vapor pressure

215 mmHg ( 37.7 °C)

Assay

98%

form

liquid

autoignition temp.

754 °F

refractive index

n20/D 1.412 (lit.)

bp

73 °C (lit.)

mp

−75 °C (lit.)

density

0.708 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C\C(C)=C(\C)C

InChI

1S/C6H12/c1-5(2)6(3)4/h1-4H3

InChI key

WGLLSSPDPJPLOR-UHFFFAOYSA-N

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General description

2,3-Dimethyl-2-butene undergoes hydrolysis to form hydroxyl radical.

Application

2,3-Dimethyl-2-butene was used in the preparation of thexyl NHC-borane (diMe-Imd-BH2thexyl).

Pictograms

FlameHealth hazard
GHS02,GHS08

Signal Word

Danger

Hazard Statements

H225,H304

Precautionary Statements

P210 - P301 + P310 + P331

Hazard Classifications

Asp. Tox. 1 - Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

17.6 °F - closed cup

Flash Point(C)

-8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Journal of the American Chemical Society, 135(38), 14433-14437 (2013-08-29)
The hydroboration of alkenes of diverse structural types by assorted N-heterocyclic carbene boranes can be accomplished by addition of 5-10% diiodine. For example, reaction of 1,3-dimethylimidazol-2-ylidene borane (diMe-Imd-BH3) with 10% I2 followed by addition of 2,3-dimethyl-2-butene provided the corresponding thexyl
Maryline Pflieger et al.
Environmental science & technology, 47(12), 6239-6246 (2013-05-15)
In order to investigate the heterogeneous oxidation kinetics of the herbicide terbuthylazine (TERB), a stable and reproducible generation system of "dark" hydroxyl radical in the gas phase was developed and optimized using a PTR-MS. TERB was adsorbed on silica particles
N Haga et al.
Photochemistry and photobiology, 61(6), 557-562 (1995-06-01)
The mechanism of photocycloaddition of 2'-deoxyuridine (1a) and thymidine (1b) to 2,3-dimethyl-2-butene (Bu) in acetonitrile by UV irradiation has been studied. The reciprocal quantum yield for the cycloaddition increased linearly with reciprocal concentrations of Bu in acetonitrile to give limiting
L R Pohl et al.
Biochemical and biophysical research communications, 117(2), 367-371 (1983-12-16)
Although indirect evidence has suggested that liver microsomal cytochrome P-450 can reductively dehalogenate several compounds to carbene metabolites, there has been no direct proof for the formation of these reactive species. We report in this paper that carbenes can be
R Tolando et al.
Xenobiotica; the fate of foreign compounds in biological systems, 26(4), 425-435 (1996-04-01)
1. During anaerobic reductive incubation of liver microsomes, from either the pyridine- or phenobarbital-treated rat, with 1,1-dichloro-1-fluoroethane (HCFC-141b) in the presence of a NADPH-regenerating system, a time- and dose-dependent formation of reactive metabolites was detected as indicated by a depletion
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