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Merck

Biotreatment of waste gas containing pyridine in a biofilter.

Bioresource technology (2006-07-04)
R A Pandey, K V Padoley, S S Mukherji, S N Mudliar, A N Vaidya, A S Rajvaidya, T V Subbarao
ABSTRACT

Industrial waste gas emissions containing pyridine are generated from pyridine manufacturing industries, and in industrial operations where pyridine is used as a solvent, as an intermediate for synthesis and as a catalyst for a variety of applications. Pyridine has unpleasant fishy odor with an odor index of 2390 and waste gaseous emissions containing pyridine require proper treatment prior to discharge. A biofilter, packed with compost and wood chips and inoculated with Pseudomonas pseudoalcaligenes-KPN for enrichment of pyridine-degrading microorganisms, was operated on a continuous feed basis for a period of more than 2 years. The results indicate that the biofilter medium with optimal moisture content of 68% and an effective bed retention time (EBRT) of 28.50s could degrade pyridine effectively (>99%) at a loading of 434 g pyridine m(-3)h(-1). The treated waste gas was also found to be free from pyridine odor.

MATERIALS
Product Number
Brand
Product Description

Supelco
Pyridine solution, certified reference material, 2000 μg/mL in methanol
Sigma-Aldrich
Pyridine, ≥99%
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Pyridine, analytical standard
Sigma-Aldrich
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Pyridine, suitable for HPLC, ≥99.9%
Sigma-Aldrich
Pyridine, ACS reagent, ≥99.0%
Sigma-Aldrich
Pyridine, biotech. grade, ≥99.9%
Sigma-Aldrich
Pyridine, ACS reagent, ≥99.0%