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11324-U

Supelco

Carboxen® Adsorbent

matrix Carboxen® 564, 20-45 mesh, pack of 144 × 290 mg

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About This Item

UNSPSC Code:
23201100
NACRES:
SB.54

product line

Carboxen®

form

powder

packaging

pack of 144 × 290 mg

technique(s)

LPLC: suitable

surface area

~400 m2/g

matrix

Carboxen® 564

matrix active group

carbon

particle size

20-45 mesh

pore size

~0.13 cm3/g mesoporosity
~0.14 cm3/g macroporosity
~0.24 cm3/g microporosity
~6-9 Å pore diameter

density

~0.61 g/mL (free fall density)

separation technique

reversed phase

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General description

Carboxens are a highly engineered synthetic carbon adsorbent engineered from polymeric precursors. These particles will not plastically deform like resins or generate fines like activated carbon. These materials are shipped and stored dried. These derivatized resins bring value to a wide range of purification applications for removing both small and large molecule impurities. They find use in both gas and liquid phase purifications. Some examples include removal of homogenous catalysts from active pharmaceutical ingredients (API)s, high-risk impurities in biochemical purifications such as host cell proteins from mAbs, removal of toxic heavy metals, purification of chlorinated molecules, and removal of extractables and leachables. Tapered pores result in increased thermodynamic and kinetic properties for both adsorption and desorption. The Carboxens vary in the relative percentage of pore structures (micro, meso, and macro), surface area, and surface pH.

Features and Benefits

Features and Benefits:

  • Spherical
  • Hard (ball pan hardness >98%)
  • Stable up to 400°C
  • High purity
  • Easy to pack
  • Stable over entire pH range
  • Do not create backpressure
  • High osmotic shock stability
  • Tapered pore sizing (from macro- to meso- to micro-)

Other Notes

For more information, please visit: specialty Carbon Adsorbents

Footnote

Pack of 144 ampules

Legal Information

Carboxen is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

11 - Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Applications of Solid Phase Microextraction.
Pawliszyn J.
Science, 64-65 (1999)
B D Page et al.
Journal of chromatography. A, 873(1), 79-94 (2000-04-11)
The headspace solid-phase microextraction (HS-SPME) efficiencies from vegetable oil of the recently available Carboxen-poly(dimethylsiloxane) (PDMS) and divinylbenzene-Carboxen-PDMS fibres were found to be much greater than those of the PDMS fibre for a number of volatile contaminants. Using these Carboxen-based fibres
Dawn M Chapman et al.
Journal of agricultural and food chemistry, 52(17), 5431-5435 (2004-08-19)
A rapid and automated solid phase microextraction (SPME) stable isotope dilution gas chromatography/mass spectrometry (GC-MS) method for 2-methoxy-3-isobutylpyrazine (MIBP) quantification in red wine was developed. Wines with 30% (w/v) NaCl and 2-methoxy-(2)H(3)-3-isobutylpyrazine internal standard were sampled with a 2 cm
Shih-Wei Tsai et al.
Journal of chromatography. A, 991(1), 1-11 (2003-04-22)
The solid-phase microextraction (SPME) device was used as a time-weighted average (TWA) sampler for ethylene oxide. Carboxen/polydimethylsiloxane (CAR/PDMS) fiber was used and hydrogen bromide (HBr) was loaded onto the fiber. The SPME fiber assembly was then inserted into PTFE tubing
Lucia Giordano et al.
Journal of chromatography. A, 1017(1-2), 141-149 (2003-10-31)
A new method was developed for the determination of 2-furfural (2-F) and 5-methylfurfural (5-MF), two products of Maillard reaction in vinegar, with head-space solid-phase microextraction (HS-SPME) coupled to gas chromatography-mass spectrometry (GC-MS). A divinylbenzene (DVB)/carboxen (CAR)/polydimethylsiloxane (PDMS) fibre was used
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