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530565

Sigma-Aldrich

Polyaniline (emeraldine salt)

composite (20 wt.% polyaniline on carbon black)

Synonym(s):

PANI

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About This Item

MDL number:
UNSPSC Code:
12352103
NACRES:
NA.23

contains

proprietary organic sulfonic acid

conductivity

30 S/cm (pressed pellet)

mp

>300 °C (lit.)

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General description

Inherently conducting polymer based additive. Stable up to at least 300°C in air. Polyaniline is environmentally stable and with tunable conductivity. Synthesis of polyaniline (PANI) emeraldine salt by chemical oxidation has been reported. It was observed that sulfonated dyes chemically interact with the charged backbone of PANI. PANI selectively adsorbs the sulfonated dye. Spectral, diffraction and conductivity measurements of the polymer has been reported in the same study.
Polyaniline (emeraldine salt) (PANI-ES) is a conductive polymer that is loaded with carbon that forms a composite where the nano-carbon is of 100 nm size. It has an emeraldine type oxidation state that exists in the form of its base. It is mainly used in the development of electrochemical devices.

Application

Conductive additive for thermoplastics and thermosets.
PANI can be used in the formation of a conjugating system that finds potential applications in semiconductors. It can be used in the fabrication of a variety of devices which include fuel cells, light emitting diodes supercapacitors, chemical sensors(10) and rechargeable batteries.(11)

Packaging

Packaged in glass bottles

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Conduction in polyaniline emeraldine salt in the terahertz region: A temperature dependence study
Tapia A and Tominaga K
Chemical Physics Letters, 598, 39-42 (2014)
Synthesis and characterization of metal oxide-polyaniline emeraldine salt based nanocomposite.
Kumar K, et al.
AIP Conference Proceedings, 1512(1), 166-167 null
Conductive polymer-carbon-imidazolium composite: a simple means for constructing solid-state dye-sensitized solar cells
Ikeda N, et al.
Chemical Communications (Cambridge, England), 1733-1735 (2006)
Supercapacitors based on flexible graphene/polyaniline nanofiber composite films
Wu Q, et al.
ACS Nano, 4(4), 1963-1970 (2010)
Carbon nanotube/polyaniline composite as anode material for microbial fuel cells
Qiao Y, et al.
Journal of Power Sources, 170(1), 79-84 (2007)

Articles

The application of conducting polymers at the interface with biology is an exciting new trend in organic electronics research.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

Research focuses on sustainable and cost-effective power generation systems to meet the growing demand for environmentally friendly energy sources.

For several decades, the need for an environmentally sustainable and commercially viable source of energy has driven extensive research aimed at achieving high efficiency power generation systems that can be manufactured at low cost.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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