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379247

Sigma-Aldrich

Tetradecafluorohexane

A mixture of perfluorinated hexanes, 95%

Synonym(s):

Perfluorohexane

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About This Item

Linear Formula:
CF3(CF2)4CF3
CAS Number:
355-42-0
Molecular Weight:
338.04
Beilstein:
1802113
EC Number:
206-585-0
MDL number:
MFCD00000437
UNSPSC Code:
12352100
PubChem Substance ID:
24863232
NACRES:
NA.22

Assay

95%

form

liquid

impurities

5% perfluoropentane

refractive index

n20/D 1.252 (lit.)

bp

58-60 °C (lit.)

mp

-74 °C (lit.)

density

1.669 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20

InChI key

ZJIJAJXFLBMLCK-UHFFFAOYSA-N

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General description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Application

Tetradecafluorohexane may be used as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution.

Other Notes

Contains perfluorocyclohexane

Hazard Statements

H412

Precautionary Statements

P273 - P501

Hazard Classifications

Aquatic Chronic 3

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Koichi Kitaguchi et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 30(6), 687-690 (2014-06-13)
A fluorocarbon and hydrocarbon organic solvent mixture is known as a temperature-induced phase-separation solution. When a mixed solution of tetradecafluorohexane as a fluorocarbon organic solvent and hexane as a hydrocarbon organic solvent (e.g., 71:29 volume ratio) was delivered in a
Liselotte M Kornmann et al.
Molecular imaging and biology : MIB : the official publication of the Academy of Molecular Imaging, 10(5), 264-270 (2008-06-10)
We investigated in vitro the potential of macrophages to act as targeted vehicle for ultrasound molecular imaging. Murine bone marrow-derived macrophages (BMM), incubated for 3 h with different concentrations of perfluorohexane (PFH) emulsions, were monitored by microscopy, flow cytometry, and
Reaction of hexafluorobenzene and tetradecafluorohexane with lithium amalgam.
Kavan L and Dousek FP.
Journal of Fluorine Chemistry, 41(3), 383-391 (1988)
Perfluorohexane-encapsulated mesoporous silica nanocapsules as enhancement agents for highly efficient high intensity focused ultrasound (HIFU).
Xia Wang et al.
Advanced materials (Deerfield Beach, Fla.), 24(6), 785-791 (2012-01-10)
Ondine S von Ehrenstein et al.
Reproductive toxicology (Elmsford, N.Y.), 27(3-4), 239-245 (2009-05-12)
Polyfluoroalkyl chemicals (PFCs) comprise a group of man-made organic compounds, some of which are persistent contaminants with developmental toxicity shown in laboratory animals. There is a paucity of human perinatal exposure data. The US EPA conducted a pilot study (Methods
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